Crystals springing into action: metal–organic framework CUK-1 as a pressure-driven molecular spring

Author:

Iacomi Paul12345ORCID,Lee Ji Sun6789,Vanduyfhuys Louis10111213ORCID,Cho Kyung Ho6789,Fertey Pierre141516ORCID,Wieme Jelle10111213ORCID,Granier Dominique12345ORCID,Maurin Guillaume12345ORCID,Van Speybroeck Veronique10111213ORCID,Chang Jong-San6789ORCID,Yot Pascal G.12345ORCID

Affiliation:

1. ICGM

2. University Montpellier

3. CNRS

4. ENSCM

5. F-34095 Montpellier

6. Research Center for Nanocatalysts

7. Korea Research Institute of Chemical Technology

8. Daejeon 305-600

9. Korea

10. Centre for Molecular Modeling

11. Ghent University

12. B-9052 Zwijnaarde

13. Belgium

14. Synchrotron Soleil

15. F-91192 Gif-sur-Yvette cedex

16. France

Abstract

Mercury porosimetry and in situ high pressure single crystal X-ray diffraction revealed the wine-rack CUK-1 MOF as a unique crystalline material capable of a fully reversible mechanical pressure-triggered structural contraction.

Funder

Agence Nationale de la Recherche

Fonds Wetenschappelijk Onderzoek

Universiteit Gent

H2020 European Research Council

Global Frontier Hybrid Interface Materials

National Research Council of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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