C(sp3)–H bond functionalization with styrenes via hydrogen-atom transfer to an aqueous hydroxyl radical under photocatalysis-Reference-Cited by-同舟云学术

C(sp3)–H bond functionalization with styrenes via hydrogen-atom transfer to an aqueous hydroxyl radical under photocatalysis

Published:2021 Issue:10 Volume:23 Page:3575-3580
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Mori Shogo¹²³⁴^ORCID,Saito Susumu¹²³⁴⁵^ORCID

Affiliation:

1. Graduate School of Science

2. Nagoya University

3. Chikusa

4. Japan

5. Research Center for Materials Science

Abstract

The redox-neutral addition of α-C–H bonds to styrenes was enabled via the hydrogen-atom transfer to aqueous hydroxyl radical generated by the oxidation of water under silver-nanoparticle-loaded titania photocatalysis.

Funder

Asahi Glass Foundation

Ministry of Education, Culture, Sports, Science and Technology

Nagoya University

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC00753J

Reference57 articles.

1. Proton-coupled electron transfer: classification scheme and guide to theoretical methods

2. Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis

3. Photocatalytic hydrogen atom transfer: the philosopher's stone for late-stage functionalization?

4. Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope

5. The past, present, and future of the Yang reaction

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