CO2 atmosphere enables efficient catalytic hydration of ethylene oxide by ionic liquids/organic bases at low water/epoxide ratios-Reference-Cited by-同舟云学术

CO2 atmosphere enables efficient catalytic hydration of ethylene oxide by ionic liquids/organic bases at low water/epoxide ratios

Published:2021 Issue:9 Volume:23 Page:3386-3391
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Ding Tong¹²³⁴⁵,Zha Jinyin²⁶³⁴⁵,Zhang Dawei¹²³⁴⁵,Zhang Jingshun¹²³⁴⁵,Yuan Huixia¹²³⁴⁵,Xia Fei²⁶³⁴⁵^ORCID,Gao Guohua¹²³⁴⁵^ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes

2. School of Chemistry and Molecular Engineering

3. East China Normal University

4. Shanghai

5. China

6. NYU-ECNU Center for Computational Chemistry at New York University Shanghai

Abstract

CO₂ as a cocatalyst enabled efficient catalytic hydration of ethylene oxide (EO) at a low H₂O/EO ratio of 1.5 : 1 along with 97% selectivities of monoethylene glycol catalyzed by ionic liquids and organic bases.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC00758K

Reference45 articles.

1. Ethylene glycol: properties, synthesis, and applications

2. A roadmap for renewable C2–C3 glycols production: a process engineering approach

3. Recent achievements in direct ethylene glycol fuel cells (DEGFC)

4. IHS Markit , Ethylene Glycols, Chemical Economics Handbook , https://ihsmarkit.com/products/ethylene-glycols-chemical-economics-handbook.html

5. Investigation of three types of catalysts for the hydration of ethylene oxide (EO) to monoethylene glycol (MEG)

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