Iron(ii) complexes of tris(2-pyridylmethyl)amine (TPMA) and neutral bidentate ligands showing thermal- and photo-induced spin crossover

Author:

García-López Víctor1234,Waerenborgh João C.56789ORCID,Vieira Bruno J. C.56789ORCID,Clemente-León Miguel1234ORCID,Coronado Eugenio1234ORCID

Affiliation:

1. Instituto de Ciencia Molecular (ICMol)

2. Universidad de Valencia

3. 46980 Paterna

4. Spain

5. Centro de Ciências e Tecnologias Nucleares

6. Instituto Superior Técnico

7. Universidade de Lisboa

8. 2695-066 Bobadela LRS

9. Portugal

Abstract

Three compounds of tetradentate TPMA and a neutral bidentate ligand with non-centrosymmetric space groups exhibit spin-crossover, which can be tuned by the bidentate ligand.

Funder

European Research Council

Ministerio de Economía y Competitividad

Generalitat Valenciana

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference34 articles.

1. Spin Crossover in Transition Metal Compounds, Topics in Current Chemistry , ed. P. Gütlich and H. A. Goodwin , Springer Verlag , Berlin, Heidelberg, New York , 2004 , vol. 233–235

2. Spin-Crossover Materials: Properties and Applications , ed. M. A. Halcrow , John Wiley & Sons , Chichester, UK , 2013

3. Spin-Transition Polymers: From Molecular Materials Toward Memory Devices

4. Towards Spin Crossover Applications

5. Electrical properties and non-volatile memory effect of the [Fe(HB(pz)3)2] spin crossover complex integrated in a microelectrode device

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