Experimental and computational insights into the mechanism of the copper(<scp>i</scp>)-catalysed sulfonylative Suzuki–Miyaura reaction-Reference-Cited by-同舟云学术

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Experimental and computational insights into the mechanism of the copper(i)-catalysed sulfonylative Suzuki–Miyaura reaction

Published:2023 Issue:24 Volume:14 Page:6738-6755
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hall Callum G. J.¹²^ORCID,Sneddon Helen F.¹^ORCID,Pogány Peter¹^ORCID,Lindsay David M.²^ORCID,Kerr William J.²^ORCID

Affiliation:

1. Medicines Design, GlaxoSmithKline, Gunnels Wood Road, Stevenage, SG1 2NY, England, UK

2. Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, Scotland, UK

Abstract

A detailed study into the copper(i)-catalysed sulfonylative Suzuki–Miyaura reaction, using spectroscopic and computational techniques. The study explores key mechanistic steps and side-reactions, including a competing copper(ii)-catalysed mechanism.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01337E

Reference55 articles.

1. K. A.Scott and J. T.Njardarson , Analysis of US FDA-Approved Drugs Containing Sulfur Atoms , in Topics in Current Chemistry Collections , Sulfur Chemistry, ed. X. Jiang , Springer International Publishing , Cham , 2019 , pp. 1–34

2. Pharmaceutical and medicinal significance of sulfur (SVI)-Containing motifs for drug discovery: A critical review

3. New catalytic reactions using sulfur dioxide

4. Copper(i)-catalyzed sulfonylative Suzuki–Miyaura cross-coupling

5. Palladium-Catalyzed Aminosulfonylation of Aryl Halides

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