Organic–inorganic hybrid metallic conductors based on bis(ethylenedithio)tetrathiafulvalene cations and antiferromagnetic oxalate-bridged copper(<scp>ii</scp>) dinuclear anions-Reference-Cited by-同舟云学术

Organic–inorganic hybrid metallic conductors based on bis(ethylenedithio)tetrathiafulvalene cations and antiferromagnetic oxalate-bridged copper(ii) dinuclear anions

Published:2022 Issue:7 Volume:10 Page:2845-2852
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Zhang Bin¹^ORCID,Zhang Yan²,Wang Zheming³,Wang Dongwei⁴,Yang Deliang⁵,Gao Zengqiang⁶,Chang Guangcai⁶,Guo Yanjun⁴,Mori Takehiko⁷^ORCID,Zhao Zhijuan⁵,Liu Fen⁵,Li Qiaolian⁵,Zhu Daoben¹^ORCID

Affiliation:

1. Organic Solid Laboratory, BNLMS, CMS & Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China

2. Institute of Condensed Matter and Material Physics, Department of Physics, Peking University, Beijing, 100871, P. R. China

3. State Key Laboratory of Rare Earth Materials Chemistry and Applications, BNLMS, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, P. R. China

4. CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology, Beijing, 100190, P. R. China

5. CAS Research/Education Center for Excellence in Molecular Science, CMS & BNLMS, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China

6. BSRF, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100047, P. R. China

7. Department of Materials Science and Engineering, Tokyo Institute of Technology, O-Okayama, Tokyo 152-8552, Japan

Abstract

In (BEDT-TTF)3[Cu2(μ-C2O4)(C2O4)2(CH3OH)(H2O)], BEDT-TTF stacks in β′′ mode and shows metallic conductivity. Hydrogen bonds between antiferromagnetic oxalate-bridged binuclear anions form a square lattice. No long range order observed to 2 K.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TC/D1TC04305F

Reference58 articles.

1. Structure and properties of tris[bis(ethylenedithio)tetrathiafulvalenium]tetrachlorocopper(II) hydrate, (BEDT-TTF)3CuCl4.H2O: first evidence for coexistence of localized and conduction electrons in a metallic charge-transfer salt

2. A Molecular Paramagnetic Superconductor

3. New BETS Conductors with Magnetic Anions (BETS = bis(ethylenedithio)tetraselenafulvalene)

4. A dual-action material

5. Organic Metals and Superconductors Based on BETS (BETS = Bis(ethylenedithio)tetraselenafulvalene)

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