Remarkable stability of a molecular ruthenium complex in PEM water electrolysis

Author:

Bellini Marco1ORCID,Bösken Jonas2ORCID,Wörle Michael2ORCID,Thöny Debora2ORCID,Gamboa-Carballo Juan José23ORCID,Krumeich Frank2ORCID,Bàrtoli Francesco14,Miller Hamish A.1,Poggini Lorenzo1ORCID,Oberhauser Werner1,Lavacchi Alessandro1,Grützmacher Hansjörg2ORCID,Vizza Francesco1ORCID

Affiliation:

1. Institute of Chemistry of Organometallic Compounds – National Research Council (ICCOM-CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Florence, Italy

2. Department of Chemistry and Applied Biosciences, ETH Hönggerberg, CH-8093 Zürich, Switzerland

3. Higher Institute of Technologies and Applied Sciences (InSTEC), University of Havana, 10600 Havana, Cuba

4. Department of Biotechnology, Chemistry and Pharmacy, University of Siena, Via Aldo Moro 2, Siena, 53100, Italy

Abstract

Molecular dinuclear ruthenium complexes deposited on conducting carbon serve as active sites for the evolution of hydrogen from neutral water in a Polymer Exchange Membrane (PEM) water electrolyser.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Eidgenössische Technische Hochschule Zürich

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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