Mechanistic elucidation of monoalkyltin(iv)-catalyzed esterification

Author:

Wolzak Lukas A.12345,Hermans Joen J.62345ORCID,de Vries Folkert789105,van den Berg Keimpe J.11125,Reek Joost N. H.1314345ORCID,Tromp Moniek12345ORCID,Korstanje Ties J.12345ORCID

Affiliation:

1. Sustainable Materials Characterization

2. van 't Hoff Institute for Molecular Sciences (HIMS)

3. University of Amsterdam

4. 1098 XH Amsterdam

5. The Netherlands

6. Molecular Photonics

7. Faculty of Science and Engineering

8. Materials Chemistry – Zernike Institute for Advanced Materials

9. University of Groningen Nijenborgh 4

10. 9747 AG Groningen

11. Akzo Nobel Car Refinishes BV

12. 2171 AJ Sassenheim

13. Bio-inspired, Homogeneous and Supramolecular Catalysis

14. van ‘t Hoff Institute for Molecular Sciences (HIMS)

Abstract

Monoalkyltin-catalyzed esterification was studied under industrially relevant catalytic conditions and was found to have a monomeric active species, with both a monomeric and a dimeric resting state.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference33 articles.

1. J. Otera and J.Nishikido , Esterification. Methods, Reactions, and Applications , Wiley-VCH Verlag GmbH & Co. , Weinheim , 2nd edn, 2010

2. J. Clayden , N.Greeves and S.Warren , Organic Chemistry , Oxford University press , Oxford , 2nd edn, 2012

3. J. J. Li , Fischer-Speier esterification, in Name Reactions , Springer , Berlin, Heidelberg , 2002

4. Organotin Compounds in Technology and Industry

5. Sn(iv)-based organometallics as catalysts for the production of fatty acid alkyl esters

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