Modulating the water oxidation catalytic activity of iridium complexes by functionalizing the Cp*-ancillary ligand: hints on the nature of the active species

Author:

Gatto Giordano1234,De Palo Alice564,Carrasco Ana C.789,Pizarro Ana M.789ORCID,Zacchini Stefano1011124ORCID,Pampaloni Guido564,Marchetti Fabio564ORCID,Macchioni Alceo1234ORCID

Affiliation:

1. Department of Chemistry, Biology and Biotechnology and CIRCC

2. University of Perugia

3. 06123 Perugia

4. Italy

5. Dipartimento di Chimica e Chimica Industriale University of Pisa

6. 56124 Pisa

7. IMDEA Nanociencia

8. 28049 Madrid

9. Spain

10. Dipartimento di Chimica Industriale “Toso Montanari”

11. Università di Bologna

12. 40136 Bologna

Abstract

A comparative study on the behavior of a series of iridium dimeric WOCs with modified Cp* ligands reveals the key role played by the variable substituent.

Funder

Università degli Studi di Perugia

Ministero dell’Istruzione, dell’Università e della Ricerca

Regione Umbria

Università di Pisa

European Commission

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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