Boron carbonitride with tunable B/N Lewis acid/base sites for enhanced electrocatalytic overall water splitting

Author:

Shi Dong1234,Chang Bin12345,Ai Zizheng12346ORCID,Jiang Hehe1234,Chen Fuzhou1234,Shao Yongliang12346ORCID,Shen Jianxing67384ORCID,Wu Yongzhong12346ORCID,Hao Xiaopeng12346ORCID

Affiliation:

1. State Key Laboratory of Crystal Materials

2. Shandong University

3. Jinan

4. P. R. China

5. Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of Shandong

6. Department of Materials Science and Engineering

7. Qilu University of Technology (Shandong Academy of Science)

8. 250353

Abstract

Lewis acid–base theory and DFT results showed that different enrichment degrees of B and N elements in BCN can improve the adsorption energy of OH*/H2O. BCN exhibits optimum electrocatalytic overall water splitting performance after adjustments.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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