Can a gas phase contact ion pair containing a hydrocarbon carbocation be formed in the ground state?

Author:

Araújo José R.12345,de Andrade Railton B.12345,Batista Hélcio J.1675ORCID,Ventura Elizete12345ORCID,do Monte Silmar A.12345ORCID

Affiliation:

1. Departamento de Química

2. CCEN

3. Universidade Federal da Paraíba

4. João Pessoa

5. Brazil

6. Universidade Federal Rural de Pernambuco

7. Recife

Abstract

So far, no conclusive evidence of a ground-state contact ion-pair containing a hydrocarbon carbocation has been given in the gas phase.

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Financiadora de Estudos e Projetos

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference109 articles.

1. A Correlation Between the Rates of Unimolecular Pyrolysis of Alkyl Halides in the Gaseous Phase and S NI Rates in Solution

2. A.Maccoll , Theoretical Organic Chemistry , Butterworths , London , 1958 , p. 230

3. A.Maccoll , in The Transition State , special publication no. 16, The Chemical Society , London , 1962

4. C. K.Ingold , Structure and Mechanism in Organic Chemistry , G. Bell and Sons, Ltd. , London , 1963

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