Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons

Author:

Topić Filip12345ORCID,Lisac Katarina51617ORCID,Arhangelskis Mihails1234ORCID,Rissanen Kari516ORCID,Cinčić Dominik178910ORCID,Friščić Tomislav1234ORCID

Affiliation:

1. Department of Chemistry

2. McGill University

3. Montreal

4. Canada

5. University of Jyväskylä

6. Finland

7. Faculty of Science

8. University of Zagreb

9. Zagreb

10. Croatia

Abstract

Trimorphic cocrystals, i.e. multi-component molecular crystals with three polymorphic structures, are exceedingly rare. First example of a trimorphic halogen-bonded cocrystal, reported here, shows a critical role for the interaction orthogonality.

Funder

Jyväskylän Yliopisto

Government of Canada

McGill University

Hrvatska Zaklada za Znanost

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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