Hydroxy and surface oxygen effects on 5-hydroxymethylfurfural oxidation to 2,5-furandicarboxylic acid on β-MnO2: DFT, microkinetic and experiment studies

Author:

Tharat Bunrat1,Ngamwongwan Lappawat1,Seehamongkol Theerada2,Rungtaweevoranit Bunyarat2ORCID,Nonkumwong Jeeranan2,Suthirakun Suwit1ORCID,Faungnawakij Kajornsak2ORCID,Chanlek Narong3,Plucksacholatarn Aunyamanee2,Nimsaila Weerawan2,Prommin Chanatkran1,Junkaew Anchalee2ORCID

Affiliation:

1. School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, Thailand 30000

2. National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), 111 Thailand Science Park, Pathum Thani, Thailand 12120

3. Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima, 30000, Thailand

Abstract

Active surface oxygen and hydroxyl groups play a decisive role in catalyzing the oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) over β-MnO2.

Funder

National Nanotechnology Center

National Research Council of Thailand

Thailand Graduate Institute of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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