Multiple CO2 reduction mediated by heteronuclear metal carbide cluster anions RhTaC2−-Reference-Cited by-同舟云学术

Multiple CO₂ reduction mediated by heteronuclear metal carbide cluster anions RhTaC₂⁻

Published:2022 Issue:30 Volume:51 Page:11491-11498
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

He Xing-Yue¹,Liu Yun-Zhu²³⁴,Wang Si-Dun⁵,Lan Xingwang¹,Li Xiao-Na²⁴^ORCID,He Sheng-Gui²³⁴^ORCID

Affiliation:

1. Key Laboratory of Chemical Biology of Hebei Province, College of Chemistry and Environmental Science, Hebei University, Baoding, Hebei, 071002, P.R. China

2. State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

3. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

4. Beijing National Laboratory for Molecular Sciences and CAS Research/Education Center of Excellence in Molecular Sciences, Beijing 100190, China

5. School of Chemistry and Chemical Engineering, South China University of Technology, 381 Wushan Road, Tianhe District, Guangzhou 510641, China

Abstract

A RhTaC2− cluster can reduce four CO2 molecules consecutively. The pivotal roles of Rh–Ta synergy and the C2 ligand in driving CO2 reduction were rationalized. A fundamental strategy to alleviate carbon deposition in the CO2 atmosphere was provided.

Funder

National Key Research and Development Program of China

Youth Innovation Promotion Association of the Chinese Academy of Sciences

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01612E

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1. Emerging trends in porous materials for CO2 capture and conversion