Direct cyanomethylation of aliphatic and aromatic hydrocarbons with acetonitrile over a metal loaded titanium oxide photocatalyst-Reference-Cited by-同舟云学术

Direct cyanomethylation of aliphatic and aromatic hydrocarbons with acetonitrile over a metal loaded titanium oxide photocatalyst

Published:2017 Issue:12 Volume:7 Page:2457-2466
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Wada Emiko¹²³⁴⁵,Takeuchi Tomoaki¹²³⁴,Fujimura Yuki⁶⁷⁸⁹⁴,Tyagi Akanksha¹²³⁴,Kato Tatsuhisa¹²³⁴¹⁰,Yoshida Hisao¹²³⁴¹¹^ORCID

Affiliation:

1. Graduate School of Human and Environmental Studies

2. Kyoto University

3. Kyoto 606-8501

4. Japan

5. Research Fellow of the Japan Society for the Promotion of Science

6. Department of Applied Chemistry

7. Graduate School of Engineering

8. Nagoya University

9. Nagoya

10. Institute for Liberal Arts and Science

11. Elemental Strategy Initiative for Catalysts and Batteries (ESICB)

Abstract

The direct cyanomethylation of aliphatic hydrocarbons proceeds with a Pt/TiO₂ photocatalyst, while that of benzene requires a Pd/TiO₂ hybrid catalyst.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY00365J

Reference31 articles.

1. Lewis Base-catalyzed Cyanomethylation of Carbonyl Compounds with (Trimethylsilyl)acetonitrile

2. Synthesis of α-Aryl Nitriles through Palladium-Catalyzed Decarboxylative Coupling of Cyanoacetate Salts with Aryl Halides and Triflates

3. Palladium-Catalyzed Decarboxylative Arylation of Potassium Cyanoacetate: Synthesis of α-Diaryl Nitriles from Aryl Halides

4. Photochemical aromatic cyanomethylation: aromatic substitution by way of radical cations

5. A Robust Nickel Catalyst for Cyanomethylation of Aldehydes: Activation of Acetonitrile under Base-Free Conditions

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