Reactions of [(dmpe)2MnH(C2H4)]: synthesis and characterization of manganese(i) borohydride and hydride complexes-Reference-Cited by-同舟云学术

Reactions of [(dmpe)2MnH(C2H4)]: synthesis and characterization of manganese(i) borohydride and hydride complexes

Published:2020 Issue:29 Volume:49 Page:9983-9994
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Price Jeffrey S.¹²³⁴,DeJordy Declan M.¹²³⁴,Emslie David J. H.¹²³⁴^ORCID,Britten James F.⁵²³⁴

Affiliation:

1. Department of Chemistry

2. McMaster University

3. Hamilton

4. Canada

5. McMaster Analytical X-ray Diffraction Facility (MAX)

Abstract

Reactions of trans-[(dmpe)₂MnH(C₂H₄)] with hydroboranes and phosphines afforded manganese(i) borohydride and hydride complexes; reaction pathways, structures and bonding are discussed.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01726D

Reference74 articles.

1. Hydrido, alkyl, and ethylene 1,2-bis(dimethylphosphino)ethane complexes of manganese and the crystal structures of MnBr2(dmpe)2, [Mn(AlH4)(dmpe)2]2 and MnMe2(dmpe)2

2. Alkyl, hydrido, and tetrahydroaluminato complexes of manganese with 1,2-bis(dimethylphosphino)ethane (dmpe). X-Ray crystal structures of Mn2(µ-C6H11)2(C6H11)2(µ-dmpe), (dmpe)2Mn(µ-H)2AlH(µ-H)2AlH(µ-H)2-Mn(dmpe)2, and Li4{MnH(C2H4)[CH2(Me)PCH2CH2PMe2]2}2·2Et2O

3. [(dmpe)2MnH(C2H4)] as a Source of a Low-Coordinate Ethyl Manganese(I) Species: Reactions with Primary Silanes, H2, and Isonitriles

4. Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride Complexes

5. Covalent transition metal, lanthanide, and actinide tetrahydroborate complexes

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