Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes
Author:
Affiliation:
1. Centro de Innovación en Química Avanzada (ORFEO-CINQA) and Departamento de Química Orgánica e Inorgánica
2. Universidad de Oviedo
3. 33071 Oviedo
4. Spain
5. Departamento de Química Física y Analítica
Abstract
The silylene- and germylene-decorated phosphanes 1Si and 2Ge have been prepared and their coordination abilities have been proven by reactions with transition-metal complexes.
Funder
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01727B
Reference81 articles.
1. Transition-Metal Complexes Featuring Dianionic Heavy Group 14 Element Aromatic Ligands
2. Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations
3. Bis(amidinato)- and bis(guanidinato)silylenes and silylenes with one sterically demanding amidinato or guanidinato ligand: synthesis and reactivity
4. Reactions of Hydrosilanes with Transition Metal Complexes
5. The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes
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