Control of triplet state generation in heavy atom-free BODIPY–anthracene dyads by media polarity and structural factors

Author:

Filatov Mikhail A.12345ORCID,Karuthedath Safakath678910ORCID,Polestshuk Pavel M.11121314ORCID,Callaghan Susan12345,Flanagan Keith J.12345,Telitchko Maxime12345,Wiesner Thomas12345,Laquai Frédéric678910ORCID,Senge Mathias O.12345ORCID

Affiliation:

1. School of Chemistry

2. SFI Tetrapyrrole Laboratory

3. Trinity Biomedical Sciences Institute

4. Trinity College Dublin

5. The University of Dublin

6. King Abdullah University of Science and Technology (KAUST)

7. KAUST Solar Center (KSC)

8. Physical Sciences and Engineering Division (PSE)

9. Material Science and Engineering Program (MSE)

10. Thuwal 23955-6900

11. Department of Chemistry

12. M.V. Lomonosov Moscow State University

13. Moscow 119991

14. Russia

Abstract

Heavy atom-free BODIPY–anthracene dyads show triplet excited state formation via PeT, controlled by molecular rotation and environmental polarity.

Funder

Science Foundation Ireland

Irish Research Council

King Abdullah University of Science and Technology

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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