A new mechanism for allylic alcohol isomerization involving ruthenium nanoparticles as a ‘true catalyst’ generated through the self-assembly of supramolecular triruthenium clusters
Author:
Affiliation:
1. Casali Center of Applied Chemistry
2. Institute of Chemistry
3. The Hebrew University of Jerusalem
4. Jerusalem 91904
5. Israel
Abstract
A new five step mechanism has been established for allylic alcohol isomerization involving ruthenium nanoparticles as the ‘true catalyst’.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA14658A
Reference48 articles.
1. Enantioselective Isomerization of Allylic Alcohols Catalyzed by a Rhodium/Phosphaferrocene Complex
2. Highly Efficient Redox Isomerization of Allylic Alcohols at Ambient Temperature Catalyzed by Novel Ruthenium-Cyclopentadienyl Complexes—New Insight into the Mechanism
3. Homogeneously catalysed isomerisation of allylic alcohols to carbonyl compounds
4. Hydrogenation and Redox Isomerization of Allylic Alcohols Catalyzed by a New Water-Soluble Pd–tetrahydrosalen Complex
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