Dual roles of sub-nanometer NiO in alkaline hydrogen evolution reaction: breaking the Volmer limitation and optimizing d-orbital electronic configuration-Reference-Cited by-同舟云学术

Dual roles of sub-nanometer NiO in alkaline hydrogen evolution reaction: breaking the Volmer limitation and optimizing d-orbital electronic configuration

Published:2023 Issue:8 Volume:10 Page:2913-2920
ISSN:2051-6347
Container-title:Materials Horizons
language:en
Short-container-title:Mater. Horiz.

Author:

Guo Fei¹^ORCID,Zhang Zeyi¹,Chen Runzhe¹,Tan Yangyang¹,Wu Wei¹,Wang Zichen¹,Zeng Tang¹,Zhu Wangbin¹,Lin Caoxin¹,Cheng Niancai¹^ORCID

Affiliation:

1. College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China

Abstract

In this work, NiO nanoclusters were simulated by DFT for reducing the free energy of water dissociation and optimizing the Pt d-orbital electronic configuration, accelerating the alkaline HER kinetics.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2023/MH/D3MH00416C

Reference58 articles.

1. Reversing the charge transfer between platinum and sulfur-doped carbon support for electrocatalytic hydrogen evolution

2. Single platinum atoms embedded in nanoporous cobalt selenide as electrocatalyst for accelerating hydrogen evolution reaction

3. Efficient dual-function catalysts for triiodide reduction reaction and hydrogen evolution reaction using unique 3D network aloe waste-derived carbon-supported molybdenum-based bimetallic oxide nanohybrids