Eu(iii) and Cm(iii) tetracarbonates – in the quest for the limiting species in solution
Author:
Affiliation:
1. University of Wrocław
2. Faculty of Chemistry
3. 50-383 Wrocław
4. Poland
5. Karlsruhe Institute of Technology
6. Institute of Nuclear Waste Disposal
7. 76021 Karlsruhe
8. Germany
Abstract
The luminescence spectra of solids [C(NH2)3][Y:M(CO3)4]·2H2O (M = Eu, Cm) were used to establish the stoichiometry and stability of the limiting species of the aqueous Eu(iii) and Cm(iii) carbonate systems at different temperatures and in a broad range of ionic strengths.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04836J
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