Reactivity of free N-heterocyclic carbenes in dichloromethane-Reference-Cited by-同舟云学术

Reactivity of free N-heterocyclic carbenes in dichloromethane

Published:2023 Issue:39 Volume:52 Page:13864-13867
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Buchner Magnus R.¹^ORCID,Bekiş Deniz F.¹^ORCID

Affiliation:

1. Anorganische Chemie, Nachwuchsgruppe Berylliumchemie, Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35032 Marburg, Germany

Abstract

The decomposition rates of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene and 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene in dichloromethane are slow enough to facilitate reactions with the free carbenes and Lewis acids.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02702C

Reference34 articles.

1. A stable crystalline carbene

2. Electron Distribution in a Stable Carbene

3. Stabilization of Fully Reduced Iron−Sulfur Clusters by Carbene Ligation: The [FenSn]0Oxidation Levels (n= 4, 8)

4. Polyhedral Ferrous and Ferric Siloxanes

5. Rare Examples of Fe(IV) Alkyl-Imide Migratory Insertions: Impact of Fe—C Covalency in (Me2IPr)Fe(═NAd)R2 (R = neoPe, 1-nor)

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Mono‐Ortho‐Beryllated Carbodiphosphoranes: Synthesis, Structure, Bonding and Reactivity;Chemistry – A European Journal;2024-04-29

2. A Preference for Heterolepticity ‐ Schlenk Type Equilibria in Organometallic Beryllium Systems;Chemistry – A European Journal;2023-09-27