Borane-catalyzed selective dihydrosilylation of terminal alkynes: reaction development and mechanistic insight-Reference-Cited by-同舟云学术

Borane-catalyzed selective dihydrosilylation of terminal alkynes: reaction development and mechanistic insight

Published:2021 Issue:32 Volume:12 Page:10883-10892
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Guoqiang¹^ORCID,Su Xiaoshi¹,Gao Liuzhou¹,Liu Xueting¹,Li Guoao¹,Li Shuhua¹^ORCID

Affiliation:

1. Institute of Theoretical and Computational Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Abstract

A B(C6F5)3/silane-based system enables the chemoselective dihydrosilylation of terminal alkynes. Using a combination of different types of hydrosilanes, a series of unsymmetrical or symmetrical 1,1-bis(silanes) could be constructed.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02769G

Reference74 articles.

1. The Chemistry of Organic Silicon Compounds , ed. Z. Rappoport and Y. Apeloig , Wiley , New York , 1998 , vol. 2 , p. 1687

2. Reactivity Studies of 3,3-Bis(trimethylsilyl)-2-methyl-1-propene in Lewis Acid-Catalyzed Allylation Reactions

3. Synthesis of Functionalized γ-Lactone via Sakurai exo-Cyclization/Rearrangement of 3,3-Bis(silyl) Enol Ester with a Tethered Acetal

4. Unique Steric Effect of Geminal Bis(silane) To Control the High Exo-selectivity in Intermolecular Diels–Alder Reaction

Cited by 19 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Copper‐Catalyzed Regiodivergent Asymmetric Difunctionalization of Terminal Alkynes;Angewandte Chemie International Edition;2024-08-19

2. Copper‐Catalyzed Regiodivergent Asymmetric Difunctionalization of Terminal Alkynes;Angewandte Chemie;2024-08-19

3. Recent advances in earth-abundant transition metal-catalyzed dihydrosilylation of terminal alkynes;Frontiers in Chemistry;2024-05-27

4. Copper-Catalyzed Formal Dihydrosilylation of Terminal Alkynes: A C(sp)–H Silylation-Hydrosilylation-Hydrogenation Sequence;ACS Catalysis;2024-05-08

5. Acid Promoted Tetrafunctionalization of Terminal Alkynes: Geminal Diazidation and Dibromination;Organic Letters;2024-04-28