A promising low pressure methanol synthesis route from CO2 hydrogenation over Pd@Zn core

A promising low pressure methanol synthesis route from CO2 hydrogenation over Pd@Zn core–shell catalysts

Published:2017 Issue:1 Volume:19 Page:270-280
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Liao Fenglin¹²³⁴⁵,Wu Xin-Ping⁶⁷⁸⁹¹⁰^ORCID,Zheng Jianwei¹¹¹²¹³¹⁴¹⁵,Li Molly Meng-Jung¹²³⁴⁵,Kroner Anna¹⁶¹⁷¹⁸⁵,Zeng Ziyan²¹⁹²⁰²¹,Hong Xinlin²¹⁹²⁰²¹,Yuan Youzhu¹¹¹²¹³¹⁴¹⁵,Gong Xue-Qing⁶⁷⁸⁹¹⁰,Tsang Shik Chi Edman¹²³⁴⁵

Affiliation:

1. Wolfson Catalysis Centre

2. Department of Chemistry

3. University of Oxford

4. Oxford

5. UK

6. Key Laboratory for Advanced Materials

7. Centre for Computational Chemistry and Research Institute of Industrial Catalysis

8. College of Chemistry and Molecular Engineering

9. East China University of Science and Technology

10. Shanghai 200237

11. State Key Laboratory of Physical Chemistry of Solid Surfaces

12. National Engineering Laboratory for Green Chemical Production of Alcohols-Ethers-Esters

13. iChEM

14. College of Chemistry and Chemical Engineering

15. Xiamen University

16. Diamond Light Source Ltd

17. Harwell Science and Innovation

18. Didcot

19. Wuhan University

20. Wuhan 430072

21. P.R. China

Abstract

We report a new Pd@Zn core–shell catalyst that offers a significantly higher kinetic barrier to CO/H₂O formation in CO₂ hydrogenation but facilitates CH₃OH production at below 2 MPa with CH₃OH selectivity at 70% as compared to 10% over Cu catalysts.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/GC/C6GC02366E

Reference37 articles.

1. Beyond Oil and Gas: The Methanol Economy

2. Assessment of Methanol Synthesis Utilizing Exhaust CO2 for Chemical Storage of Electrical Energy

3. The stability of Cu/ZnO-based catalysts in methanol synthesis from a CO2-rich feed and from a CO-rich feed

4. Synthesis of Methanol

5. Production of synthesis gas

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