Facet-dependent peroxo species regulate product distribution and H2O2utilization in CeO2-catalyzed aniline oxidation-Reference-Cited by-同舟云学术

Facet-dependent peroxo species regulate product distribution and H₂O₂utilization in CeO₂-catalyzed aniline oxidation

Published:2023 Issue:26 Volume:11 Page:14034-14042
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Tian Linyuan¹,Liao Yin-Song²³,Chou Jyh-Pin⁴^ORCID,Tan Zicong¹,Chen Jian Lin⁵^ORCID,Lee Jung-Hoon⁶^ORCID,Benedict Lo Tsz Woon⁷^ORCID,Peng Yung-Kang¹⁸^ORCID

Affiliation:

1. Department of Chemistry, City University of Hong Kong, Hong Kong

2. Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan

3. Tsing Hua Interdisciplinary Program, National Tsing Hua University, Hsinchu 300, Taiwan

4. Department and Graduate Institute of Physics, National Changhua University of Education, Changhua 500, Taiwan

5. Department of Applied Science, School of Science and Technology, Hong Kong Metropolitan University, Hong Kong

6. Department of Chemistry, Soonchunhyang University, Asan 31538, Korea

7. Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong

8. City University of Hong Kong Chengdu Research Institute, Chengdu, China

Abstract

We showed that the coordination structure of the Ce sites affects the configuration (and reactivity) of the surface peroxo species in H2O2activation, which determines the product distribution and H2O2utilization in the aniline oxidation reaction.

Funder

National Science and Technology Council

Research Grants Council, University Grants Committee

Sichuan Province Science and Technology Support Program

Soonchunhyang University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D3TA02486E

Reference42 articles.