Combining alkali metals and zinc to harness heterometallic cooperativity in cyclic ester ring-opening polymerisation

Author:

Gruszka Weronika1234,Lykkeberg Anna1234,Nichol Gary S.1234ORCID,Shaver Michael P.56789ORCID,Buchard Antoine1011124ORCID,Garden Jennifer A.1234ORCID

Affiliation:

1. EaStCHEM School of Chemistry

2. University of Edinburgh

3. Edinburgh

4. UK

5. School of Natural Sciences

6. Department of Materials

7. Henry Royce Institute

8. University of Manchester

9. Manchester

10. Department of Chemistry

11. University of Bath

12. Bath

Abstract

Cooperative heterotrimetallic Na/Zn2 and K/Zn2 complexes combine the excellent activities and control of the homometallic analogues, giving “best of both” in cyclic ester ring-opening polymerisation.

Funder

Engineering and Physical Sciences Research Council

Ramsay Memorial Fellowships Trust, University College London

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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