Coordination chemistry of phosphinocarbynes: phosphorus vs. carbyne site selectivity

Author:

Colebatch Annie L.1234ORCID,Hill Anthony F.1234ORCID

Affiliation:

1. Research School of Chemistry

2. Australian National University

3. Canberra

4. Australia

Abstract

The phosphinocarbyne complex [W(CPPh2)(CO)2(Tp*)] (1: Tp* = hydrotris(dimethylpyrazolyl)borate) coordinates transition metal fragments via the phosphine to form bimetallic species [W{CPPh2RhCl2(Cp*)}(CO)2(Tp*)] (2) and [W(CPPh2AuCl)(CO)2(Tp*)] (3).

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference55 articles.

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5. Thioxoethenylidene (CCS) as a Bridging Ligand

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