Real-time structural dynamics of the ultrafast solvation process around photo-excited aqueous halides

Author:

Markmann Verena1ORCID,Pan Jaysree1ORCID,Hansen Bianca L.1ORCID,Haubro Morten L.1ORCID,Nimmrich Amke12ORCID,Lenzen Philipp1,Levantino Matteo3ORCID,Katayama Tetsuo45ORCID,Adachi Shin-ichi67,Gorski-Bilke Simone8,Temps Friedrich8ORCID,Dohn Asmus O.19ORCID,Møller Klaus B.1ORCID,Nielsen Martin M.1ORCID,Haldrup Kristoffer1ORCID

Affiliation:

1. Technical University of Denmark, Anker Engelunds Vej 1, 2800 Lyngby, Denmark

2. Department of Chemistry and Molecular Biology, University of Gothenburg, Gothenburg, Sweden

3. European Synchrotron Radiation Facility, CS40220, Grenoble 38043 Cedex 9, France

4. Japan Synchrotron Radiation Research Institute, Kouto 1-1-1, Sayo, Hyogo 679-5198, Japan

5. RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan

6. Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan

7. Department of Materials Structure Science, School of High Energy Accelerator Science, 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan

8. Christian-Albrechts-University Kiel, Olshausenstr. 40, 24098 Kiel, Germany

9. Science Institute, University of Iceland, 107 Reykjavík, Iceland

Abstract

Time-resolved X-ray solution scattering with a 1-photon and 2-photon pump qualitatively confirms the ∼0.5 Å increase in the nearest-neighbour halide–oxygen distances of iodide and bromide solvated in water.

Funder

Japan Society for the Promotion of Science

Novo Nordisk Fonden

Rannís

Danmarks Frie Forskningsfond

Publisher

Royal Society of Chemistry (RSC)

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