Photo-induced cation translocation in a molecular shuttle based on a calix[4]-biscrown including DCM and DMABN chromophores

Author:

Dozova Nadia12345,Kumar Rajesh6789,Pradhan Tuhin6789,Lacombat Fabien12345,Valeur Bernard10111213,Kim Jong Seung6789,Plaza Pascal12345

Affiliation:

1. Ecole Normale Supérieure-PSL Research University

2. Département de Chimie

3. Sorbonne Universités – UPMC Univ Paris 06

4. CNRS UMR 8640 PASTEUR

5. 75005 Paris

6. Department of Chemistry

7. Korea University

8. Seoul 136-701

9. Korea

10. Département CASER

11. Conservatoire National des Arts et Métiers

12. Paris

13. France

Abstract

A K+ ion bound to the DCM-grafted crown of a new ditopic molecular shuttle is shown to be phototranslocated towards the DMABN site.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference30 articles.

1. Biological Applications of Photochemical Switches, ed. H. Morrison, John Wiley & Sons, New York, 1993

2. Molecular Switches, ed. B. L. Feringa, Wiley-VCH, Weinheim, 2001

3. Special Issue on Molecular Machines, Acc. Chem. Res., 2001, 34

4. V. Balzani , M.Venturi and A.Credi, Molecular Devices and Machines, Wiley-VCH, Weinheim, 2003

5. Light powered molecular machines

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