Substituent-controlled, mild oxidative fluorination of iodoarenes: synthesis and structural study of aryl I(iii)- and I(v)-fluorides-Reference-Cited by-同舟云学术

Substituent-controlled, mild oxidative fluorination of iodoarenes: synthesis and structural study of aryl I(iii)- and I(v)-fluorides

Published:2019 Issue:30 Volume:10 Page:7251-7259
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Häfliger Joel¹²³⁴,Pitts Cody Ross¹²³⁴^ORCID,Bornemann Dustin¹²³⁴,Käser Roland¹²³⁴,Santschi Nico¹²³⁴^ORCID,Charpentier Julie¹²³⁴,Otth Elisabeth¹²³⁴,Trapp Nils¹²³⁴,Verel René¹²³⁴^ORCID,Lüthi Hans Peter¹²³⁴,Togni Antonio¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Applied Biosciences

2. ETH Zürich

3. 8093 Zürich

4. Switzerland

Abstract

This mild TCICA/KF oxidative fluorination approach provides controllable access to aryl-IF₂and aryl-IF₄compounds, thus allowing detailed structural studies.

Funder

Eidgenössische Technische Hochschule Zürich

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02162K

Reference48 articles.

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2. Straightforward Syntheses of Hypervalent Iodine(III) Reagents Mediated by Selectfluor

3. Deconstructing the Catalytic, Vicinal Difluorination of Alkenes: HF-Free Synthesis and Structural Study of p-TolIF2

4. Organic Polyvalent Iodine Compounds

5. Hypervalent iodine(III) reagents in organic synthesis

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