Reversible-deactivation radical polymerization of vinyl acetate mediated by tralen, an organomediator

Author:

Chang Chun-Wei1,Jen Yu-Yu1,Tang Shan-Cheng1,Zhang Pan2,Chen Changle2ORCID,Peng Chi-How1ORCID

Affiliation:

1. Department of Chemistry and Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsinchu, 30013, Taiwan

2. CAS Key Laboratory of Soft Matter Chemistry, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, People's Republic of China

Abstract

An organic compound, tralen, has been developed as a mediator to control the radical polymerization of vinyl acetate, methyl acrylate, and N-vinyl pyrrolidone via the reversible termination mechanism.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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