Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species-Reference-Cited by-同舟云学术

Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species

Published:2020 Issue:48 Volume:49 Page:17719-17724
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Macha Bret B.¹²³⁴⁵,Dhara Debabrata¹²³⁴⁵^ORCID,Radacki Krzysztof¹²³⁴⁵,Dewhurst Rian D.¹²³⁴⁵,Braunschweig Holger¹²³⁴⁵^ORCID

Affiliation:

1. Institute for Inorganic Chemistry

2. Julius-Maximilians-Universität Würzburg

3. Am Hubland

4. Germany

5. Institute for Sustainable Chemistry & Catalysis with Boron

Abstract

We report the synthesis of group 6 borylene complexes by the salt elimination method and study their borylene transfer capability to other transition metal fragments, providing new borylene complexes that are inaccessible by other routes.

Funder

FP7 Ideas: European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03557B

Reference61 articles.

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3. Synthesis and Structure of the First Transition Metal Borylene Complexes

4. Electron-Precise Coordination Modes of Boron-Centered Ligands

5. Transition metal borylene complexes: boron analogues of classical organometallic systems

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