Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species

Author:

Macha Bret B.12345,Dhara Debabrata12345ORCID,Radacki Krzysztof12345,Dewhurst Rian D.12345,Braunschweig Holger12345ORCID

Affiliation:

1. Institute for Inorganic Chemistry

2. Julius-Maximilians-Universität Würzburg

3. Am Hubland

4. Germany

5. Institute for Sustainable Chemistry & Catalysis with Boron

Abstract

We report the synthesis of group 6 borylene complexes by the salt elimination method and study their borylene transfer capability to other transition metal fragments, providing new borylene complexes that are inaccessible by other routes.

Funder

FP7 Ideas: European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference61 articles.

1. F. A. Cotton and G.Wilkinson , Advanced Inorganic Chemistry , Wiley , New York , 5th edn, 1988

2. J. P. Collman , L. S.Hegedus , J. R.Norton and R. G.Finke , Principles and Applications of Organotransition Metal Chemistry , University Science Books , Mill Valley , 1987

3. Synthesis and Structure of the First Transition Metal Borylene Complexes

4. Electron-Precise Coordination Modes of Boron-Centered Ligands

5. Transition metal borylene complexes: boron analogues of classical organometallic systems

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1. On Neutral Unsaturated Ouroboric Borylenes;The Journal of Physical Chemistry A;2022-07-29

2. Group VI Metal Complexes of Carbon Monoxide and Isocyanides;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2021

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