Dithiolato- and halogenido-bridged nickel–iron complexes related to the active site of [NiFe]-H2ases: preparation, structures, and electrocatalytic H2 production
Author:
Affiliation:
1. Department of Chemistry
2. State Key Laboratory of Elemento-Organic Chemistry
3. College of Chemistry
4. Nankai University
5. Tianjin 300071
Abstract
A new series of [NiFe]-H2ase mimics (5a,b–7a,b) has been prepared and structurally characterized; particularly, they have been found to be pre-catalysts for H2 production from Cl2CHCO2H under CV conditions.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02203D
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