Electrophilic fluoroalkylthiolation induced diastereoselective and stereospecific 1,2-metalate migration of alkenylboronate complexes-Reference-Cited by-同舟云学术

Electrophilic fluoroalkylthiolation induced diastereoselective and stereospecific 1,2-metalate migration of alkenylboronate complexes

Published:2020 Issue:30 Volume:11 Page:8020-8024
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Shen Feng¹²³⁴⁵^ORCID,Lu Long²⁴⁶,Shen Qilong¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Organofluorine Chemistry

2. Shanghai Institute of Organic Chemistry

3. University of Chinese Academy of Sciences

4. Chinese Academy of Sciences

5. Shanghai 200032

6. China

Abstract

A transition metal free process for conjunctive functionalization of alkenylboron ate-complexes with electrophilic fluoroalkylthiolating reagents affords β-tri- and difluoroalkylthiolated boronic esters in good yield and diastereoselectivity.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC03039B

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