Practical synthesis of polysubstituted unsymmetric 1,10-phenanthrolines by palladium catalyzed intramolecular oxidative cross coupling of C(sp2)–H and C(sp3)–H bonds of carboxamides-Reference-Cited by-同舟云学术

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Practical synthesis of polysubstituted unsymmetric 1,10-phenanthrolines by palladium catalyzed intramolecular oxidative cross coupling of C(sp2)–H and C(sp3)–H bonds of carboxamides

Published:2019 Issue:4 Volume:6 Page:544-550
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Sun Wen-Wu¹²³⁴,Liu Ji-Kai¹²³⁴,Wu Bin¹²³⁴^ORCID

Affiliation:

1. School of Pharmaceutical Sciences

2. South-Central University for Nationalities

3. Wuhan 430074

4. China

Abstract

A short sequence for the practical synthesis of polysubstituted unsymmetric 1,10-phenanthrolines was developed based on palladium-catalyzed oxidative cross coupling of C(sp²)–H/C(sp³)–H bonds of carboxamides.

Funder

National Natural Science Foundation of China

South-Central University of Nationalities

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C8QO01290C

Reference59 articles.

1. J. A. McCleverty and T. J.Meyer , Comprehensive coordination chemistry II , Elsevier Ltd. , 2004

2. 1,10-Phenanthroline: a versatile ligand

3. MLCT excited states of cuprous bis-phenanthroline coordination compounds

4. 1,10-Phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes

5. 1,10-Phenanthroline: A versatile building block for the construction of ligands for various purposes

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1. Cyclization Through Dual C(sp³)−H Functionalization;Advanced Synthesis & Catalysis;2024-08-22

2. Fifty Shades of Phenanthroline: Synthesis Strategies to Functionalize 1,10-Phenanthroline in All Positions;Chemical Reviews;2024-05-15

3. Nucleophilic Aliphatic Substitution 2019;Organic Reaction Mechanisms Series;2023-01-20

4. Oxidation and Reduction;Organic Reaction Mechanisms Series;2023-01-20

5. Iridium-catalyzed Enantioselective Intramolecular Cross-dehydrogenative Coupling of Alkyl Aryl Ethers Giving Enantioenriched 2,3-Dihydrobenzofurans;Chemistry Letters;2022-06-05

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