Trisubstituted alkenes with a single activator as dipolarophiles in a highly diastereo- and enantioselective [3+2] cycloaddition with vinyl epoxides under Pd-catalysis-Reference-Cited by-同舟云学术

Trisubstituted alkenes with a single activator as dipolarophiles in a highly diastereo- and enantioselective [3+2] cycloaddition with vinyl epoxides under Pd-catalysis

Published:2018 Issue:93 Volume:54 Page:13143-13146
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Du Juan¹²³⁴⁵,Jiang Yang-Jie¹²³⁴⁵,Suo Jia-Jia¹²³⁴⁵,Wu Wen-Qiong¹²³,Liu Xiu-Yan¹²³,Chen Di¹²³,Ding Chang-Hua¹²³⁶⁷^ORCID,Wei Yin¹²³^ORCID,Hou Xue-Long¹²³⁸³^ORCID

Affiliation:

1. State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry (SIOC), Chinese Academy of Sciences (CAS)

2. Shanghai 200032

3. China

4. University of Chinese Academy of Sciences

5. Beijing 100049

6. Department of Chemistry, Innovative Drug Research Center, Shanghai University

7. Shanghai 200444

8. Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, SIOC, CAS

Abstract

1,1,2-Trisubstituted alkenes with a single activator were used in the Pd-catalyzed asymmetric cycloaddition of vinyl epoxides with high diastereo- and enantioselectivities.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Research Grants Council, University Grants Committee

Croucher Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC07996J

Reference54 articles.

1. B. Olofsson and P.Somfai , in Aziridines and Epoxides in Organic Synthesis , ed. A. K. Yudin , Wiley-VCH , Weinheim , 2006 , pp. 315–347

2. Regio- and Stereoselective Ring Opening of Allylic Epoxides

3. Vinyl Epoxides in Organic Synthesis

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