Aerobic intramolecular carbon–hydrogen bond oxidation promoted by Cu(i) complexes-Reference-Cited by-同舟云学术

Aerobic intramolecular carbon–hydrogen bond oxidation promoted by Cu(i) complexes

Published:2020 Issue:41 Volume:49 Page:14647-14655
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Álvarez María¹²³⁴⁵^ORCID,Molina Francisco¹²³⁴⁵,Fructos Manuel R.¹²³⁴⁵^ORCID,Urbano Juan⁶³⁴⁵^ORCID,Álvarez Eleuterio⁷⁸⁹⁵^ORCID,Sodupe Mariona¹⁰¹¹¹²⁵^ORCID,Lledós Agustí¹⁰¹¹¹²⁵^ORCID,Pérez Pedro J.¹²³⁴⁵^ORCID

Affiliation:

1. Laboratorio de Catálisis Homogénea

2. Unidad Asociada al CSIC CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química

3. Universidad de Huelva

4. 21007-Huelva

5. Spain

6. Departamento de Química

7. Instituto de Investigaciones Químicas

8. Centro de Investigaciones Isla de la Cartuja

9. 41092 Sevilla

10. Departament de Química

11. Universitat Autònoma de Barcelona

12. Barcelona

Abstract

The complex TpMsCu(THF) undergoes the intramolecular oxidation of an alkylic C–H bond with O₂, leading to the formation of a trinuclear compound where alkoxy and hydroxyl ligands are bonded to the copper centres.

Funder

Ministerio de Economía y Competitividad

Universidad de Huelva

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03198D

Reference43 articles.

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3. Mechanisms Whereby Mononuclear Copper Proteins Functionalize Organic Substrates

4. Multicopper Oxidases and Oxygenases

5. Oxidations by copper metalloenzymes and some biomimetic approaches

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