Ruthenium complexes with triazenide ligands bearing an N-heterocyclic moiety, and their catalytic properties in the reduction of nitroarenes

Author:

Romero-Soto Christian A.1,Iglesias Ana L.2ORCID,Velázquez-Ham Amor F.1,Camarena-Díaz Juan P.1,Correa-Ayala Erick1,Gomez-Lopez Jessica L.1,Chávez Daniel1,Ochoa-Terán Adrián1ORCID,Aguirre Gerardo1,Rheingold Arnold L.3,Grotjahn Douglas B.4ORCID,Parra-Hake Miguel1,Miranda-Soto Valentín1ORCID

Affiliation:

1. Tecnológico Nacional de México/Instituto Tecnológico de Tijuana/Centro de Graduados e Investigación en Química, Blvd. Alberto Limón Padilla S/N, 22454 Tijuana, BC, Mexico

2. Facultad de Ciencias de la Ingeniería y Tecnología, Universidad Autónoma de Baja California, Mexico

3. Department of Chemistry and Biochemistry, University of California at San Diego, CA 92093, USA

4. Department of Chemistry and Biochemistry, San Diego State University, CA 92182, USA

Abstract

Ruthenium complexes (RuCat) of triazenide ligands bearing different N-heterocyclic moieties catalyze the hydrogenation of a myriad of substituted nitroarenes under mild reaction conditions.

Funder

Consejo Nacional de Ciencia y Tecnología

Tecnológico Nacional de México

Publisher

Royal Society of Chemistry (RSC)

Reference60 articles.

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2. G.Booth , Nitro Compounds, Aromatics , in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH, Verlag GmbH & Co. KGaA , Weinheim , 2012 , vol. 24 , pp. 301–347

3. P. F.Vogt , Amines, Aromatic , in Ullmann's Encyclopedia of Industrial Chemistry ; Wiley-VCH, Verlag GmbH & Co. KGaA , Weinheim , 2012 , vol. 2 , pp. 699–716

4. Z.Wang , Béchamp Reduction , in Comprehensive Organic Name Reactions and Reagents , John Wiley & Sons Inc. , 2010 , pp. 284–287

5. Reduction of Nitroarenes via Catalytic Transfer Hydrogenation Using Formic Acid as Hydrogen Source: A Comprehensive Review

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