Frequency control of crossover reactions in concurrent cationic vinyl-addition and ring-opening copolymerization of vinyl ethers and oxiranes: specific roles of weak Lewis bases and solvent polarity-Reference-Cited by-同舟云学术

Frequency control of crossover reactions in concurrent cationic vinyl-addition and ring-opening copolymerization of vinyl ethers and oxiranes: specific roles of weak Lewis bases and solvent polarity

Published:2015 Issue:31 Volume:6 Page:5675-5682
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Kanazawa Arihiro¹²³⁴⁵,Aoshima Sadahito¹²³⁴⁵

Affiliation:

1. Department of Macromolecular Science

2. Graduate School of Science

3. Osaka University

4. Toyonaka

5. Japan

Abstract

Weak Lewis bases and solvent polarity affected the frequency of the crossover reactions in the concurrent cationic vinyl-addition and ring-opening copolymerization of vinyl ethers and oxiranes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2015/PY/C5PY00152H

Reference36 articles.

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5. Studies on propagating species in cationic polymerization of styrene derivatives by acetyl perchlorate or iodine. II. Salt effect on the relative reactivity in the cationic copolymerization of styrene derivatives with 2-chloroethyl vinyl ether initiated by iodine

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