Mechanical insulation of aza-Pechmann dyes within [2]rotaxanes-Reference-Cited by-同舟云学术

Mechanical insulation of aza-Pechmann dyes within [2]rotaxanes

Published:2024 Issue:34 Volume:15 Page:13823-13831
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cutillas-Font Guillermo¹^ORCID,Pastor Aurelia¹^ORCID,Alajarin Mateo¹^ORCID,Martinez-Cuezva Alberto¹^ORCID,Marin-Luna Marta¹^ORCID,Batanero Belen²^ORCID,Berna Jose¹^ORCID

Affiliation:

1. Department of Organic Chemistry, Faculty of Chemistry, University of Murcia, Regional Campus of International Excellence, Campus Mare Nostrum, 30100 Murcia, Spain

2. Department of Organic Chemistry and Inorganic Chemistry, University of Alcala, Institute of Chemical Research AndrésM. del Rio, 28805 Alcalá de Henares, Madrid, Spain

Abstract

Here we demonstrate that mechanically interlocked aza-Pechmann dyes improve stability and modulate photophysical and redox properties of the non-interlocked dyes. Computational and electrochemical analyses show enhanced HOMO and LUMO stability.

Funder

Universidad de Alcalá

Fundación Séneca

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC03657C

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