Scope of the DMC mediated glycosylation of unprotected sugars with phenols in aqueous solution-Reference-Cited by-同舟云学术

Scope of the DMC mediated glycosylation of unprotected sugars with phenols in aqueous solution

Published:2020 Issue:37 Volume:18 Page:7355-7365
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Qiu Xin¹²³⁴,Fairbanks Antony J.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of Canterbury

3. Christchurch

4. New Zealand

5. Biomolecular Interaction Centre

Abstract

Activation of reducing sugars in aqueous solution using DMC and triethylamine in the presence of phenols allows direct stereoselective conversion to the corresponding 1,2-trans aryl glycosides without the need for any protecting groups.

Funder

University of Canterbury

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01727B

Reference70 articles.

1. Strategies toward protecting group-free glycosylation through selective activation of the anomeric center

2. Chemoselective Reactions for the Synthesis of Glycoconjugates from Unprotected Carbohydrates

3. Regioselective modification of unprotected glycosides

4. Unprotected Carbohydrates as Starting Material in Chemical Synthesis: Not Just a Challenge but an Opportunity

5. Mechanism in carbohydrate chemistry

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