Redox-neutral rhodium(<scp>iii</scp>)-catalyzed divergent synthesis of tetrasubstituted 1,3-enynes and alkynylated benzofurans-Reference-Cited by-同舟云学术

Redox-neutral rhodium(iii)-catalyzed divergent synthesis of tetrasubstituted 1,3-enynes and alkynylated benzofurans

Published:2023 Issue:1 Volume:21 Page:147-152
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Gong Xin¹,Yu Na²,Gu Linghui¹^ORCID,Li Zheyu¹,Ma Wenbo¹^ORCID,Zhao Fei¹³^ORCID

Affiliation:

1. Antibiotics Research and Re-evaluation Key Laboratory of Sichuan Province, Sichuan Industrial Institute of Antibiotics, School of Pharmacy, Chengdu University, Chengdu 610106, China

2. Department of Preparation Center, General Hospital of Ningxia Medical University, Yinchuan 750004, China

3. State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, 555 Zu Chong Zhi Road, Shanghai 201203, China

Abstract

Herein, we report the rhodium-catalyzed tunable divergent synthesis of tetrasubstituted 1,3-enynes and alkynylated benzofurans via C−H alkenylation/DG migration and [3 + 2] annulation, respectively.

Funder

Key Research and Development Program of Ningxia

1000 Talents Sichuan Program

Sichuan Province Science and Technology Support Program

Chengdu University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D2OB01800D