Niobium tetrahalide complexes with neutral diphosphine ligands

Author:

Benjamin Sophie L.1234,Chang Yao-Pang5674,Hector Andrew L.5674,Jura Marek89104,Levason William5674,Reid Gillian5674,Stenning Gavin89104

Affiliation:

1. School of Science and Technology

2. Nottingham Trent University

3. Nottingham NG11 8NS

4. UK

5. Chemistry

6. University of Southampton

7. Southampton SO17 1BJ

8. ISIS Neutron and Muon Source

9. STFC Rutherford Appleton Laboratory

10. Didcot

Abstract

Two series of eight coordinate tetrahaloniobium(iv) diphosphine complexes, the monomeric [NbX4(diphosphine)2] with either dodecahedral or square antiprismatic geometries, and the dimeric [Nb2X4(μ-X)4(diphosphine)2] have been characterized.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference43 articles.

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2. T. Waters , A. G.Wedd, M.Ziolek and I.Nowak, in Comprehensive Coordination Chemistry II, ed. J. A. McCleverty and T. J. Meyer, Elsevier, Oxford, 2004, vol. 4, pp. 241–312

3. W. Levason , in The Chemistry of Organophosphorus Compounds, ed. F. R. Hartley, Wiley, NY, 1990, vol. 1, pp. 568–641

4. Soft diphosphine and diarsine complexes of niobium(v) and tantalum(v) fluorides: synthesis, properties, structures and comparisons with the corresponding chlorides

5. Six-coordinate NbF5 and TaF5 complexes with tertiary mono-phosphine and -arsine ligands

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