Experimental insights into catalytic oxidation of 1,6-hexanediol to ε-caprolactone over (<i>p</i>-cymene)RuCl<sub>2</sub>(L) complexes in non-polar media-Reference-Cited by-同舟云学术

Experimental insights into catalytic oxidation of 1,6-hexanediol to ε-caprolactone over (p-cymene)RuCl₂(L) complexes in non-polar media

Published:2022 Issue:12 Volume:7 Page:2562-2572
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Promchana Pratya¹,Choojun Kittisak¹²,Leesakul Nararak³,Saithong Saowanit³,Chainok Kittipong⁴,Sooknoi Tawan¹²^ORCID

Affiliation:

1. Department of Chemistry, School of Science, King Mongkut's Institute of Technology Ladkrabang, Chalongkrung Road, Ladkrabang, Bangkok, 10520, Thailand

2. Catalytic Chemistry Research Unit, School of Science, King Mongkut's Institute of Technology Ladkrabang, Chalongkrung Road, Ladkrabang, Bangkok, 10520, Thailand

3. Division of Physical Science and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla, 90112, Thailand

4. Materials and Textile Technology, Faculty of Science and Technology, Thammasat University, Khlong Luang, Pathum Thani, 12121 Thailand

Abstract

The activity-pocket site dimension (θc) dependence of (p-cymene)RuCl2(L) supports associative interchange mechanism for 1,6-hexandiol oxidation to ε-caprolactone. Methyl isobutyl carbinol, a H-accepting product, reacts with Ru, causing deactivation.

Funder

Thailand Research Fund

National Research Council of Thailand

Center of Excellence for Innovation in Chemistry

Ministry of Higher Education, Science, Research and Innovation, Thailand

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RE/D2RE00159D

Reference62 articles.