Complete stereodivergence in the synthesis of 2-amino-1,3-diols from allenes-Reference-Cited by-同舟云学术

Complete stereodivergence in the synthesis of 2-amino-1,3-diols from allenes

Published:2014 Issue:8 Volume:5 Page:3046-3056
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Adams Christopher S.¹²³,Grigg R. David¹²³,Schomaker Jennifer M.¹²³

Affiliation:

1. Department of Chemistry

2. University of Wisconsin

3. Madison, USA

Abstract

Herein, we describe studies to understand how both reagent and substrate control can be effectively employed in the stereodivergent oxidative amination of allenes, with transfer of the axial chirality of an enantioenriched precursor to point chirality in each possible diastereomeric 2-amino-1,3-diol product.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01214C

Reference125 articles.

1. Metal-catalysed 1,2-diamination reactions

2. The enantioselective intramolecular aminative functionalization of unactivated alkenes, dienes, allenes and alkynes for the synthesis of chiral nitrogen heterocycles

3. Transition-Metal-Catalyzed Diamination of Olefins

4. A Pd(0)-Catalyzed Diamination of Terminal Olefins at Allylic and Homoallylic Carbons via Formal C−H Activation under Solvent-Free Conditions

5. Asymmetric Synthesis of Diamine Derivatives via Sequential Palladium and Rhodium Catalysis

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