Role of ligand spacer length of a tripodal amide on uranium(<scp>vi</scp>) and plutonium(<scp>iv</scp>) complexation: synthesis, solvent extraction, liquid membrane transport and theoretical studies-Reference-Cited by-同舟云学术

Role of ligand spacer length of a tripodal amide on uranium(vi) and plutonium(iv) complexation: synthesis, solvent extraction, liquid membrane transport and theoretical studies

Published:2022 Issue:44 Volume:46 Page:21221-21228
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Karak Ananda¹²,Mahanty Bholanath³^ORCID,Mohapatra Prasanta K.²³^ORCID,Musharaf Ali Sk.⁴^ORCID,Egberink Richard J. M.⁵,Sathe Darshan B.¹,Bhatt Raj B.¹,Valsala Thisur P.¹,Huskens Jurriaan⁵^ORCID,Verboom Willem⁵^ORCID

Affiliation:

1. INRPO, FF, Nuclear Recycle Board, Bhabha Atomic Research Centre, Tarapur, India

2. Homi Bhabha National Institute, Anushakti Nagar, Mumbai-400094, India

3. Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai-400085, India

4. Chemical Engineering Division, Bhabha Atomic Research Centre, Mumbai-400085, India

5. Laboratory of Molecular Nanofabrication, Department for Molecules & Materials, MESA+ Institute, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands

Abstract

Liquid–liquid extraction of several actinide and lanthanide ions, viz., U(vi), Pu(iv), Am(iii) and Eu(iii) was investigated from nitric acid feed solutions employing N,N,N′,N′,N′′,N′′-hexa-n-octyl nitrilotripropamide (HONTP) in 90% n-dodecane + 10% isodecanol.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ03354B

Reference40 articles.

1. Uranium and Plutonium Extraction by N,N-dialkylamides Using Multistage Mixer-settler Extractors

2. EFFECTS OF STRUCTURE OF N,N-DISUBSTITUTED AMIDES ON THEIR EXTRACTION OF ACTINIDE AND ZIRCONIUM NITRATES AND OF NITRIC ACID1

3. THE EXTRACTION BY N.N-DIALKYLAMIDES. II. EXTRACTION OF ACTINIDE CATIONS

4. Comparing Branched versus Straight-chained Monoamide Extractants for Actinide Recovery

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