3-Aminoperylene and ascorbate in aqueous SDS, one green laser flash … and action! Sustainably detoxifying a recalcitrant chloro-organic-Reference-Cited by-同舟云学术

3-Aminoperylene and ascorbate in aqueous SDS, one green laser flash … and action! Sustainably detoxifying a recalcitrant chloro-organic

Published:2017 Issue:11 Volume:16 Page:1613-1622
ISSN:1474-905X
Container-title:Photochemical & Photobiological Sciences
language:en
Short-container-title:Photochem. Photobiol. Sci.

Author:

Kohlmann Tim¹²³⁴,Naumann Robert¹²³⁴,Kerzig Christoph¹²³⁴,Goez Martin¹²³⁴^ORCID

Affiliation:

1. Martin-Luther-Universität Halle-Wittenberg

2. Institut für Chemie

3. D-06120 Halle (Saale)

4. Germany

Abstract

Green light releases the predator e_aq˙⁻ (the hydrated electron) at near-physiological pH through a metal-free catalytic cycle, consuming only ascorbate AscH⁻ as a sacrificial donor, and decomposing organochlorides R–Cl with high turnover numbers.

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/PP/C7PP00311K

Reference36 articles.

1. Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous Solution

2. Sustainable, inexpensive and easy-to-use access to the super-reductant e˙−aq through 355 nm photoionization of the ascorbate dianion—an alternative to radiolysis or UV-C photochemistry

3. Investigation of the reactivity of hydrated electron toward perfluorinated carboxylates by laser flash photolysis

4. Reductive Defluorination of Aqueous Perfluorinated Alkyl Surfactants: Effects of Ionic Headgroup and Chain Length

5. Efficient Reductive Dechlorination of Monochloroacetic Acid by Sulfite/UV Process

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