Biomass oxidation to formic acid in aqueous media using polyoxometalate catalysts – boosting FA selectivity by in-situ extraction-Reference-Cited by-同舟云学术

Biomass oxidation to formic acid in aqueous media using polyoxometalate catalysts – boosting FA selectivity by in-situ extraction

Published:2015 Issue:10 Volume:8 Page:2985-2990
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Reichert Jenny¹²³⁴,Brunner Birgit⁵⁶⁷⁸⁴,Jess Andreas⁵⁶⁷⁸⁴,Wasserscheid Peter¹²³⁴,Albert Jakob¹²³⁴

Affiliation:

1. Lehrstuhl für Chemische Reaktionstechnik der Universität Erlangen-Nürnberg

2. Egerlandstrasse 3

3. 91058 Erlangen

4. Germany

5. Lehrstuhl für Chemische Verfahrenstechnik der Universität Bayreuth

6. Zentrum für Energietechnik (ZET)

7. Universitätsstraße 30

8. 95440 Bayreuth

Abstract

1-Hexanol and 1-heptanol were applied asin-situextracting agents in the oxidation reaction of biomass to formic acid (FA) using a Keggin-type polyoxometalate (H8PV5Mo7O40) as a homogeneous catalyst, oxygen as the oxidant and water as the solvent.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/EE/C5EE01706H

Reference31 articles.

1. Do alternative energy sources displace fossil fuels?

2. S. Solomon , D.Qin, M.Manning, Z.Chen, M.Marquis, K.Averyt, M.Tignor and H. L.Miller, Climate Change 2007: The Physical Science Basis, Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 2007

3. Pyrolysis of biomass to produce fuels and chemical feedstocks

4. Production of Platform Chemicals and Synthesis Gas from Biomass

5. Conversion of biomass into methane gas

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