Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

Author:

Ortega-Moreno Laura12345,Peloso Riccardo12345,Maya Celia12345,Suárez Andrés12345,Carmona Ernesto12345

Affiliation:

1. Instituto de Investigaciones Químicas (IIQ)

2. Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA)

3. Universidad de Sevilla and Consejo Superior de Investigaciones Científicas (CSIC)

4. 41092 Sevilla

5. Spain

Abstract

A novel terphenylphosphine PMe2ArDipp2 (1) (Dipp = 2,6-iPr2C6H3) forms stable Pt(0) complexes with ethene and 3,3-dimethylbut-1-ene that behave as sources of the reactive Pt(PMe2ArDipp2) fragment.

Funder

Ministerio de Ciencia e Innovación

Agencia de Innovación y Desarrollo de Andalucía

Ministerio de Educación, Cultura y Deporte

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference56 articles.

1. M. Bochmann , Organometallics and Catalysis. An Introduction, Oxford University Press, Oxford, 2015

2. R. H. Crabtree , The Organometallic Chemistry of the Transition Metals, John Wiley & Sons, Inc., Hoboken, 2014

3. J. Hartwig , Organotransition Metal Chemistry: From Bonding to Catalysis, Sausalito, 2010

4. NHC ligands versus cyclopentadienyls and phosphines as spectator ligands in organometallic catalysis

5. C. A. McAuliffe and W.Levason, Phosphine, Arsine and Stibine Complexes of the Transition Elements, Elsevier Scientific Pub. Co., Amsterdam, 1999

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