The mechanism of Fe induced bond stability of uranyl(v)

Author:

Vitova Tonya1ORCID,Faizova Radmila2,Amaro-Estrada Jorge I.3,Maron Laurent3,Pruessmann Tim1ORCID,Neill Thomas1,Beck Aaron1,Schacherl Bianca1ORCID,Tirani Farzaneh Fadaei2ORCID,Mazzanti Marinella2ORCID

Affiliation:

1. Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. 3640, D-76021 Karlsruhe, Germany

2. Group of Coordination Chemistry, Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland

3. LPCNO, University of Toulouse, INSA Toulouse 135, Avenue de Rangueil, Toulouse Cedex 31077, France

Abstract

The role of Fe in the increased stability of uranyl(v) is clarified by using state of the art uranium metalorganic chemistry, advanced X-ray spectroscopic approaches and computations.

Funder

H2020 European Research Council

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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